What I've Learned: Sebastian Bonaiuto
The longtime leader of the 51²č¹Ż Bands program is taking his final bow. He shared some of the most impactful lessons he'll remember from decades of playing and teaching music.
Photography byĀ Caitlin Cunningham
It Came from the Lab of Dunwei Wang
One of 51²č¹Żās most prolific researchers was just named interim director of the Schiller Institute. Heās as committed as ever to making the world a better place by harnessing the power of chemistry.
Dunwei Wang often jokes that if you choose a problem thatās easy to solve, youāll be out of a job in two years. Luckily, the celebrated chemistry professor and newly appointed Interim Director of the Schiller Institute for Integrated Science and Society has chosen to focus his twenty-year career on some of the biggest challenges facing our planet, pushing the limits of chemistry to unlock new discoveries in clean energy storage, toxic waste recycling, and plastic manufacturing. Originally from China, Wang earned his PhD at Stanford University and completed two years of postdoctoral study at the California Institute of Technology before decamping to the East Coast with his wife, also a researcher at 51²č¹Ż. He finds inspiration everywhere, whether itās outside in nature, at the dinner table with his eleven-year-old son, or in the pages of The New York Times, and delights in interdisciplinary collaboration (he once co-taught a seminar on materialism with an English professor). Many of his projects begin as conversations with student researchers, 110 of whom have passed through his lab during their time at 51²č¹Ż and worked alongside Wang to change the world for the better, one molecule at a time. Hereās a closer look at Wangās many roles and research projects at Boston College.
Wang has spent the entirety of his career at Boston College, joining the faculty in 2007 and taking over as chair of the chemistry department in 2019. This past January, he was appointed interim Seidner Family Executive Director of the Schiller Institute for Integrated Science and Society, a hub of interdisciplinary research centered around energy, health, and the environment. The Institute, which opened in 2021, offers courses, hosts events, and provides research grants to faculty, with an overarching focus on generating knowledge that serves the common good.Ā
Wang, who has been involved in the Schiller Institute since its inception, said he identifies strongly with its mission of addressing societyās most pressing challenges. āWhen I think about scientific research, I always start with the societal impact,ā he said. āWhat are the biggest problems the world faces, and with my expertise, what can I do to contribute?āĀ
In his new role, Wang hopes to leverage the Schiller Instituteās impressive resources to encourage more faculty and students to collaborate across disciplines. Its state-of-the-art laboratories, for example, could become shared spaces for student researchers in the humanities, STEM, and social sciences, Wang said, leading to the natural cross-pollination of ideas. Heād also like to make the Instituteās seed grant program more valuable to faculty by offering constructive feedback on all research proposals, similar to the peer-review process at academic journals. āThe way I see it, the Schiller Institute is a long-term investment,ā he said. āI want to get back to its essence, which is the collage of ideas and the honest exchange of thoughts.ā
On a clear day, the sun delivers enough energy to the Earth in just one hour to power the planet for an entire year, so why do we remain reliant on fossil fuels to heat our homes, run our appliances, and drive our vehicles? One answer is that while solar panels are effective at capturing the sunās rays and converting them to electricity, the process of storing that energy for future use remains costly and inefficient. Currently, most homeowners with solar panels sell excess power back to the grid, and rely on nonrenewable energy sources at night or whenever Mother Nature gives us a cloudy day. āItās unpredictable, and thatās the biggest problem,ā Wang said. āWe need a solution that can help us smooth out the intermittency of renewable energy.āĀ
The solution Wang is most excited about is inspired by a process that takes place (for free) right outside our windows. Photosynthesis, taught in every middle school science class, allows plants to convert sunlight into stored energy. Recreating this process in a labāusing abundant materials like iron and siliconācould unlock a future where solar energy produced on the roof of your home is stored on-site in chemical bonds, available whenever you need it.Ā
Wangās lab has been working to develop artificial photosynthesis for more than a decade, funded by grants from the National Science Foundation and the US Department of Energy. The project is hugely ambitious, requiring constant experimentation to create a system that is both effective at harvesting and storing energy and inexpensive enough to produce at scale. āThe majority of the time weāre evaluating different options and finding the challenges,ā Wang said. āMost of the time itās failures, thatās just the way of the lab, but my job is to help students see those as part of our success.ā
They power almost everything around us, from laptops to lawnmowers, but the chemistry that makes lithium-ion batteries so effective is also what makes them so difficult to dispose of. Unlike their alkaline forebears, which can be tossed in the trash, lithium-ion packs contain potentially hazardous heavy metals like nickel, manganese, and cobalt, which can leak out of spent battery casings and into the environment.Ā
Recycling depleted lithium-ion batteries today requires large amounts of toxic chemicals, but that could change thanks to a recent discovery made by Wang and 51²č¹Ż Associate Professor of Biology Babak Momeni. Last fall, the researchers cultivated a new bacterium, called Acidithiobacillus ferrooxidans (Atf), that feeds off of spent battery waste, naturally leaching toxic materials from iron or stainless steel casing. āOur results showed that the bacteria can actually thrive with this new food source,ā Wang said, āand the resulting solution is highly active for recycling spent batteries.ā
Wang and Momeni arenāt stopping there. With help from student researchers, theyāre building a prototype battery out of the recycled materials produced by Atf, to see if it functions as well as existing ones. The hope is to eventually develop a pack that can be recycled again and again without sacrificing performance. āItās all centered around sustainability,ā Wang said.
Few materials have received more scorn in the past decade than single-use plastics, most of which take centuries to decompose in landfills and often end up polluting our oceans and communities. But when Wangās son became passionate about the topic after a class debate in elementary school, Wang found himself playing the unlikely role of plastic-defender. āIf you go to a hospital, single-use plastic saves lives,ā he explained to his son, also pointing out that plastic wrapping, when used correctly, reduces food waste by preserving perishables. āKids tend to accept āthis is bad,ā but like anything, itās multi-dimensional.āĀ
Instead of eliminating single-use plastic, Wang wants to chemically alter the material to make it easy to break down and recycle, lessening its environmental impact. Unlike aluminum, a raw material that can be melted down repeatedly, plastics consist of multiple components that can degrade when mixed and are often difficult or costlyāif not impossibleāto separate, making recycling them a significant challenge. Wangās team is exploring a solution that involves introducing chemical modifications during the recycling process that bind the components of plastic together in a way that doesnāt compromise their integrity. The team published a proof of concept earlier this year, and while research is still in the early stages, Wang is excited by the potential impact. Plasticāboth single- and multi-useāis everywhere in our society, but only about 6 percent of plastic waste is actually recycled. The rest gets tossed in landfills, burned, or shipped to other countries, where it typically meets the same fate. Ā
āI donāt want to challenge medical professionals or manufacturers, I just wanted to challenge myself,ā Wang said. āYou give me your waste. Can I develop chemistry that can turn that waste into treasure?ā
Wang in 2012 with Rui Liu MCGSā13, one of the 110 student researchers who have worked in his lab since he joined 51²č¹Ż in 2007. Photo: Gary Wayne Gilbert
As a chemist, Wang will admit to having only one area of expertise: breaking and forming chemical bonds. Itās a skill he applies in a wide range of creative ways, including transforming low-value materials into useful ones. Several years ago, he turned his attention to lignin, one of the most abundant but underutilized byproducts of paper and wood milling. āIt accounts for about 30 percent of biomass thatās thrown away,ā Wang said, āso we thought, why not find ways to use it?ā
Working with Associate Professor of Chemistry Jia Niu, Wang developed a catalyst that uses light to break specific chemical bonds in lignin, converting it into smaller molecules called oligomers. He then combined these oligomers with molecular āgluesā known as crosslinkers to create a sustainable plastic that can be continually recycled. (Most of the plastics we use canāt be recycled at all.) Wang and Niu published their findings in ACS Central Science, in an article that has been cited more than forty times.Ā
Two former lab members are listed as coauthors on the ACS report, including Rong Chen, who pitched the original idea. āWe get in debates all the time and itās one of the parts I love most,ā Wang said. āStudents come here to learn but itās really a two-way streetātheir questions prompt me to think more deeply about my own work, and the meaning of the things weāre doing.āĀ
Feeding a global population of eight billion would be impossible without fertilizer, which provides plants with nutrients like nitrogen, phosphorus, and potassium that enable farmers to double their crop output and keep grocery shelves stocked. Unfortunately, current methods for creating fertilizer are bad for the environment. The process of making ammonia, the central ingredient in most fertilizers, has been around for more than a century, and involves mixing nitrogen from the air with hydrogen derived from natural gas. āIt has to be done at 700 degrees, under very high pressure, generating a lot of carbon dioxide,ā Wang explained. āThe reaction is ingenious but it is not clean.āĀ
But what if fertilizer could be made in a better way? Chemical synthesisāwhen two or more chemicals are combined to form a new materialāalmost always requires heat, but we shouldnāt have to burn fossil fuels to generate it, Wang said, when the sun produces it already, and for free. āIn the winter when you go out, the sun makes it feel warm, and the science is not that different,ā he said. The heat we feel is caused by tiny particles called photons, which carry electromagnetic energy from the sun to Earth. Wang is working to figure out a method to harness that same energy to drive chemical reactions, like the one that produces ammonia. Doing so could transform the chemical industry. āThe chemical plants wouldnāt have to be so large, or have huge chimneys, or burn all that natural gas,ā he said. Smaller manufacturing sites could be more widely distributed, reducing the need for transportation. āRight now we use big trucks, eighteen-wheelers, to transport fertilizer from where itās synthesized,ā he said. āThat, in and of itself, is a huge waste.ā ā½